Kozmetik atık sularından fenton prosesiyle organik madde gideriminin ve kinetiğinin incelenmesi

Yalçın Kemal Bayhan, Gökçe Didar Değermenci
593 147

Öz


Kozmetik endüstrisi atık suların arıtımı için fenton prosesinin uygulanabilirliği araştırılmıştır. Proses süresince KOİ ve TOK giderimi üzerine reaksiyon süresi, pH, sıcaklık, Fe+2 ve H2O2 konsantrasyonlarının etkileri karakterize edilmiştir. Elde edilen sonuçlara göre, 36ºC’de optimum reaksiyon süresi, pH, Fe+2 ve H2O2 konsantrasyonları sırasıyla 90 dakika, pH 3, 1 g/L, 17,5 g/L,  KOİ ve TOK giderim etkinliği ise %89,6 ve %76,9 olarak belirlenmiştir. Ayrıca, farklı sıcaklık değerleri araştırılarak prosesin kinetik analizi gerçekleştirilmiştir. Prosesin yalancı birinci dereceden reaksiyon kinetiğine uyduğu ve aktivasyon enerjisinin (Ea) 117,7 kJ/mol olduğu belirlenmiştir.


Anahtar kelimeler


Kozmetik atık suyu; fenton prosesi; oksidasyon; kinetik

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Referanslar


Bogacki J., Naumczyk J., Marcinowski P., Kucharska M., Treatment of cosmetic wastewater using physicochemical and chemical methods, Chemik, 65, 94-97, 2011.

Naumczyk J., Bogacki J., Marcinowski P., Kowalik P., Cosmetic wastewater treatment by coagulation and advanced oxidation processes, Environ. Technol., 35 (5), 541-548, 2014.

Puyol D., Monsalvo V.M., Mohedano A.F., Sanz J.L., Rodriguez J.J., Cosmetic wastewater treatment by upflow anaerobic sludge blanket reactor, J. Hazard. Mater., 185 (2-3), 1059-1065, 2011.

Bautista P., Mohedano A.F., Gilarranz M.A., Casas J.A., Rodriguez J.J., Application of Fenton oxidation to cosmetic wastewaters treatment, J. Hazard. Mater., 143 (1-2), 128-1, 2007.

Boroski M., Rodrigues A.C., Garcia J.C., Sampaio L.C., Nozaki J., Hioka N., Combined electrocoagulation and TiO2 photoassisted treatment applied to wastewater effluents from pharmaceutical and cosmetic industries, J. Hazard. Mater., 162 (1), 448-454, 2009.

Bautista P., Mohedano A.F., Menendez N., Casas J.A., Rodriguez J.J., Catalytic wet peroxide oxidation of cosmetic wastewaters with Fe-bearing catalysts, Catal. Today, 151 (1-2), 148-152, 2010.

Huisman I., Optimising UF for wastewater treatment through membrane autopsy and failure analysis, Filtr. Sep., 41 (3), 26-27, 2004.

Monsalvo V.M., Lopez J., Somer M.M., Mohedano A.F., Rodriguez J.J., Short-term fouling control by cyclic aeration in membrane bioreactors for cosmetic wastewater treatment, Desalin. Water Treat., 56 (13), 3599-3606, 2015.

Tobajas M., Polo A.M., Monsalvo V.M., Mohedano A.F., Rodriguez J.J., Analysis of the operating conditions in the treatment of cosmetic wastewater by sequencing batch reactors, Environ. Eng. Manage. J., 13 (12), 2955-2962, 2014.

Primo O., Rivero M.J., Ortiz I., Photo-Fenton process as an efficient alternative to the treatment of landfill leachates, J. Hazard. Mater., 153 (1-2), 834-842, 2008.

Neyens E., Baeyens J., A review of classic Fenton’s peroxidation as an advanced oxidation technique, J. Hazard. Mater., 98 (1-3), 33-50, 2003.

Haber F., Weiss, J., The Catalytic Decomposition of Hydrogen Peroxide by Iron Salts, Proc. R. Soc. London, Ser. A, 147 (861), 332-351, 1934.

Walling C., Fenton's reagent revisited, Acc. Chem. Res., 8 (4), 125-131, 1975.

Fenton H.J.H., LXXIII.-Oxidation of tartaric acid in presence of iron, J. chem. Soc. Trans., 65, 899-910, 1894.

Kang Y.W., Hwang K.Y., Effects of reaction conditions on the oxidation efficiency in the Fenton process, Water Res., 34 (10), 2786-2790, 2000.

Fan C., Horng C.-Y., Li S.-J. Structural characterization of natural organic matter and its impact on methomyl removal efficiency in Fenton process, Chemosphere, 93 (1), 178-183, 2013.

Zhang J., Chen S., Zhang Y., Quan X., Zhao H., Zhang Y., Reduction of acute toxicity and genotoxicity of dye effluent using Fenton-coagulation process, J. Hazard. Mater., 274, 198-204, 2014.

Lopez A., Pagano M., Volpe A., Di Pinto A.C., Fenton’s pre-treatment of mature landfill leachate, Chemosphere, 54 (7), 1005-1010, 2004.

Santana C.S., Aguiar A., Effect of biological mediator, 3-hydroxyanthranilic acid, in dye decolorization by Fenton processes, Int. Biodeterior. Biodegrad., 104, 1-7, 2015.

İSKİ Genel Müdürlüğü Atıksuların Kanalizasyona Deşarj Yönetmeliği, 2013, http://www.iski.gov.tr/web/assets/SayfalarDocs/Mevzuat%20ve%20Y%C3%B6netmelikler/ISKI_Atiksularin_Kanalizasyona_Desarj_Yonetmeligi.pdf, Erişim Tarihi Ocak 18, 2017.

Klassen N.V., Marchington D., McGowan H.C.E., H2O2 Determination by the I3‾ Method and by KMnO4 Titration, Anal. Chem., 66 (18), 2921-2925, 1994.

Clesceri L.S., Eaton A.D., ve Greenberg A.E., Standard Methods for the Examination of Water and Wastewater, American Public Health Association, California, 1998.

Talinli I., Anderson G.K., Interference of hydrogen peroxide on the standard COD test, Water Res., 26 (1), 107-110, 1992.

Elmolla E.S., Chaudhuri M., The feasibility of using combined Fenton-SBR for antibiotic wastewater treatment, Desalination, 285, 14-21, 2012.

Lin S.H., Lo C.C., Fenton process for treatment of desizing wastewater, Water Res., 31 (8), 2050-2056, 1997.

Singh S.K., Tang W.Z., Statistical analysis of optimum Fenton oxidation conditions for landfill leachate treatment, Waste Manage. (Oxford), 33 (1), 81-88, 2013.

Lucas M.S., Peres J.A., Removal of COD from olive mill wastewater by Fenton's reagent: Kinetic study, J. Hazard. Mater., 168 (2-3), 1253-1259, 2009.

Özdemir C., Öden M.K., Şahinkaya S., Güçlü D., The sonochemical decolorisation of textile azo dye CI Reactive Orange 127, Color. Technol., 127 (4), 268-273, 2011.

Tang W.Z., Huang C.P., 2,4-Dichlorophenol Oxidation Kinetics by Fenton's Reagent, Environ. Technol., 17 (12), 1371-1378, 1996.

Pérez M., Torrades F., Domènech X., Peral J., Removal of organic contaminants in paper pulp effluents by AOPs: an economic study, Jo J. Chem. Technol. Biotechnol., 77 (5), 525-532, 2002.

Eisenhauer H.R., Oxidation of phenolic wastes, J. Water Pollut. Control Fed., 36 (9), 1116-1128, 1964.

Basturk E., Karatas M., Advanced oxidation of Reactive Blue 181 solution: A comprasion between Fenton and Sono-Fenton Process, Ultrason. Sonochem., 21 (5), 1881-1885, 2014.

Okur M., Aktı F., The removal of C.I. acid vıolet 90 metal-complex dye using synthetic and natural zeolite from aqueous solutions, Journal of the Faculty of Engineering and Architecture of Gazi University, 31 (3), 677-686, 2016.

Kasiri M.B., Aleboyeh H., Aleboyeh A., Mineralization of C.I. Acid Red 14 azo dye by UV/Fe‐ZSM5/H2O2 process, Environ. Technol., 31 (2), 165-173, 2010.




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